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Chrome tanned leathers are definitely unique in comparison with leather made from any other known tanning agents, especially in terms of thermal stability, cost and its reactive mechanism with collagen fibers. In our current studies, self basifying chrome tanning materials masked with different percentages of organic acid were prepared and applied after the de-liming stage of leather processing. This eliminated the need for pickling and basification steps. Tanned leathers resisted shrinkage up to 103 and 105±2°C while conventional chrome tanned leathers resisted up to 108±2°C. Also, interaction of anionic chrome species in tanning was studied. It was observed that the percentage of anionic species in the experimental chrome tanning material was higher than conventional chrome tanning material and the shrinkage temperature achieved by application of experimental tanning material proves that anionic species do involve in tanning. Tanned leathers were crusted and analysed for strength and organoleptic properties.